Synthesis and Characterization of Nanoparticle Calcium Oxide (CaO) from Blood Calm Shell by Precipitation Methods
DOI:
https://doi.org/10.26877/asset.v6i4.765Keywords:
Calcium oxide, Nanotechnology, Blood clam shells, Precipitation, sustainable materialAbstract
Blood Clam (Anadara granosa) contains high calcium carbonate which can be utilized in various fields by being used as nanotechnology. The shell contains 98.7% CaCO3 making it a sustainable material source. The research aims to synthesize and characterize of calcium oxide nanoparticles by precipitation methods. This method begins with crushing the shell into 100 mesh as sample. Each sample is mixed with HCl solute. After mixing, each filtrate is precipitated with KOH solute to multiple pH (7 ; 9 ; 11). The method continues with neutralizing the precipitate with water until it reach pH 7 and drying it with oven in 100oC for 1 hour. The sample will be calcinated for 3 hours in various temperature (300oC ; 500oC ; 900oC). Samples will be analyzed with SEM-EDX and XRF Analysis. Research indicates that The degree of acidity and calcination temperature do not have a significant effect on calcium oxide content. The calcium oxide content is ranged between 82,58% - 87,47% with the sizes being ranged between 550 nm - 20mm.
References
Adji, N, T, L., Lucytasari, S.D., Suprihatin, 2023, 'Sintesis dan Karakterisasi Nanokalsium Oksida dari Cangkang Kerang Hijau dengan Metode Presipitasi', Jurnal Teknik Kimia, Vol. 18, No. 1, pp. 66-69.
Dewi, S. E., Eddiwan, Efawani, 2018, 'Morphometric and Growth Patterns of The Blood Clam (Anadara Granosa) From The Bagan Siapi - Api Coastal Area Rokan Hilir', Berkala Perikanan Terubuk, Vol. 46, No. 3, pp. 37-45
Handayani, L., 2020, 'Pengaruh Suhu Kalsinasi Terhadap Nilai Rendemen CaO Cangkang Tiram (Crassotrea Gigas)', Jurnal Tilapa, Vol.1, No. 1, pp 1-6.
Hastuti, Y.P., Djokosetiyanto, D., Permatasari, I., 2012, 'Penambahan kapur CaO pada Media Bersalinitas untuk Penambahan Benih Ikan Patin Pangasius Hypopthalmus', Jurnal Akuakultur Indonesia, Vol. 11, No. 2, pp 168-178.
Hosokawa, M, 2018, Nanoparticle Technology Handbook 3rd Edition, Amsterdam, Joe Hayton.
Ilhamudin, M., Hilyana, S., Astriana, B.H., 2019, 'Pengaruh Tingkat Kerapatan Mangrove Terhadap Pertumbuhan dan Kelangsungan Hidup Kerang Darah (Anadara granosa)', Jurnal Perikanan, Vol. 9, No.1, pp. 75-85.
Jamilah, Ahmad, R., Ernita, M., 2020, 'Penggunaan Pupuk Cair Chromolaena odorata dan Kalium dalam Menekan Kehampaan dan Meningkatkan hasil Padi Ungu Black Madras', Jurnal Agronida, Vol. 6, No. 1, pp. 55 - 63.
Pangestu, T.O, 202, 'Sintesis dan Karakterisasi Kalsium Fosfat dari Cangkang Bekicot denganMetode Presipitasi', CHEESA: Chemical Engineering Research Articles, Vol. 4, No.2, pp. 82 - 88.
Purwasasmita, B.S., Gultom, R.S., 2008, 'Sintesis dan Karakterisasi Serbuk Hidroksiapatit Skala Lab Sub-Mikron Menggunakan Metode Presipitas', Bionatura: Jurnal Imu Hayati dan Fisik, Vol. 10, No. 2, pp. 155 - 167.
Sunardi, S, 2020, 'Sintesis dan Karakterisasi Nanokalsium Oksida dari Cangkang Telur', Alchemy Jurnal Kimia, Vol. 16, No. 2, pp. 250 - 259.
Wahyuningsih, K., Jumeri, Wagiman, 2018, 'Green Catalyst Activities of CaO Nanoparticles from Pinctada maxima Shell on Alcoholysis Reaction', Eksakta; Jurnal Ilmu - Ilmu MIPA, Vol. 18, No. 2, pp. 121 - 136.
Zuraidah, S., Adi, L, O, S., Hastono, B, Soemantoro, 2015, 'Limbah Cangkang Kerang Sebagai Substitusi Agregat Kasar Pada Campuran Beton', Prosiding Seminar Nasional Aplikasi Teknologi Prasarana Wilayah (ATPW), pp. 117.
Anggelina, E. Zabrina, F.N., Pujiastuti, C., Muljanie, S., Sumada, K., 2024. 'Sintesa dan Karakterisasi Nanopartikel Kalsium Oksida dari Cangkang Telur dengan Metode Presipitasi', Jurnal Teknik Kimia, Vol. 18, No. 2, pp.127-132.
Nika, J., Anisah, A., Saleh, R. 2019. 'Pemanfaatan Limbah Cangkang Kerang HIjau dengan Variai Suhu Pembakaran sebagai Bahan Pengganti Sebagian Semen Pada Pembuatan Beton', Jurnal Pendidikan Teknik Bangunan, Vol. 1, No. 14, pp. 10-17.
Rosalina, M. 2022. 'Synthesis and Modification of Nano-Precipitated Calcium Carbonate (PCC) with Addition of Ethylene Glycol', International Journal of Eco-Innovation in Science and Engineering, Vol. 1, No.3, pp. 35-40.
Zahra, M.F., Hiyahara, I.A., Syaima, H., 2023. 'Mini review: Sintesis dan Karakterisasi Nanopartikel CaO dari Cangkang Telur Menggunakan Metode Kalsinasi', Prosiding Seminar Nasional Kimia dan Terapan III, pp. 74-78.
Syah, M., 2022. 'Sintesis dan Karakterisasi Dolomit Nanopartikel Tinggi CaO-MgO Sebagai bahan Baku Penyerap Logam Berat', Serambi Engineering, Vol. 7. No. 2, pp. 3229 - 3235.
Romadhona, G.N., Syafira, N.P., Gumelar, T., Rizqiyah, V.F., Ningrum, E.O, 2023. 'Sintesis dan karakterisasi Hidroksiapatit Cangkang Rajungan dengan Variasi Suhu Kalsinasi dan Konsentasi KH2PO4 menggunakan Metode Presipitasi Sebagai Sediaan Biomaterial Implan Tylang', Prosiding Seminar Nasional Teknik Kimia "Kejuangan", Vol. 5, No.1, pp. 1-5.
Alobaidi, Y.M., Ali, M., Mohammed, A.M., 2022. 'Synthesis of Calcium Oxide Nanoparticles from waste eggshells by Thermal Decomposition and their Application', Jordan J Bio Sci, Vol 15, No. 2, pp. 264-274.
Masime, J.O., Ogur, E.O., Mbatia, B.N., Aluoch, A.P., Otieno, G. 2022. 'Characterization of Eggshells Nanocatalyst: Synthesized by bottom-up Technology', Walisongo Journal of Chemistry, Vol.5, No.2, pp. 202-211.
